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Photochemical Chloro-Sulfoximidation of Bicyclo1.1.1pentanes with Sulfonimidoyl Chlorides | Synapse

May 15, 2026Chemical Communications0 citations

Photochemical Chloro-Sulfoximidation of Bicyclo1.1.1pentanes with Sulfonimidoyl Chlorides

GYGao-feng YangNanjing University MKMengting KouWuhan University of Technology ZLZhi LiuNanjing University

Key Points

This research aims to develop a synthetic method for creating disubstituted bicyclo[1.1.1]pentane sulfoximines using sulfonimidoyl chlorides.
Developed a photochemical reaction platform for chloro-sulfoximidation
Examined the reactivity of various sulfonimidoyl chlorides with BCPs
Evaluated the efficiency of the synthesis process
Successfully synthesized disubstituted BCP sulfoximines
Demonstrated high yields in multiple reaction conditions
Established the versatility of sulfonimidoyl chlorides as reagents

Abstract

Bicyclo1.1.1pentanes (BCPs) and sulfoximines are versatile bioisosteres in organic synthesis and medicinal chemistry. However, direct synthetic methods for accessing disubstituted BCP sulfoximines remain limited. Herein, we report a general platform...

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Cite This Study

Yang et al. (Thu,) studied this question.

synapsesocial.com/papers/6a06b81ce7dec685947aa9d2 https://doi.org/https://doi.org/10.1039/d6cc01651k