Randomized trial examines non-equilibrium polymer dynamics, indicating significant factors like architecture and molar mass.
∼ 0.02, i.e., pore diameters that are much larger than the chain dimensions. This reflects non-equilibrium configurations of the adsorbed layer that extent away from the pore walls. The equilibrium times depend strongly on temperature, pore size, and functionality. In general, star-shaped polymers require longer times to reach equilibrium because of the higher tendency for adsorption. Both thermal protocols produced an increasing dielectric strength for the segmental and chain modes. The increase was beyond any densification, suggesting enhanced orientation correlations of subchain dipoles.
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Kardasis et al. (2022) studied this question.
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