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Minireview highlights redox behavior of NOx ligands and their role in palladium-mediated oxidation processes.
This Minireview highlights the redox and non-innocent behavior of NO(x) ligands (x=1, 2, or 3) in selected Pd-mediated processes, for example, alkene and aromatic oxidation processes. A focus is placed on mechanistic understanding and linking recent transformations, such as C-H bond activation/functionalization and Wacker oxidation, with previous work on the functionalization of aromatics and alkenes by Pd(II) salts.
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Ian J. S. Fairlamb (2015) studied this question.
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