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Dynamic photoprogramming of paintable liquid crystal photonic devices with multi-stability shows practical application in smart soft materials and responsive optics. However, there exist three key challenges that limit their development: achieving precise paintability with controllable viscosity and resolution, maintaining well-ordered liquid crystal photonic structures, and enabling multi-stable photoresponsive behavior. Here, we address these limitations by incorporating an intrinsic photoswitch into a cellulose-based liquid crystal system, further constructing a unique paintable helical photonic architecture featuring both multi-stability and dynamic light-actuation. The intrinsic chiral photoswitch enables multi-stable modulation of helical pitch, while optimized viscosity restrains the remarkable fluidity of traditional liquid crystal systems and matches proper surface anchoring, thereby allowing for paintability and programming of a photonic device. The cutting-edge single-step painting enables highly efficient, large-area and well-defined patterning of helical architectures on diverse flexible substrates, thereby promoting prospective applications in anti-counterfeiting, information encryption, and smart window-film. This strategy establishes a robust and versatile foundation that integrates practical explorations in soft matter photonics with state-of-the-art engineering applications, such as multifunctional interactive optical information systems and advanced intelligent flexible sensors.
Hu et al. (Thu,) studied this question.