Functional Adaptability and Durability Performance of Chinese Traditional Concrete Across Multiple Structural Layers in Chongwu Ancient City Wall, Quanzhou, China

Chinese Traditional Concrete (CTC), known as “San-he-tu,” has ensured the long-term durability of ancient coastal structures, yet its underlying material design logic remains insufficiently understood. This study investigates the Chongwu Ancient City Wall (Quanzhou, China), a Ming Dynasty granite fortification exposed to over 600 years of marine weathering, to elucidate the structure–property–function relationships of CTC across three functional layers: the horse-track surface, wall core backfill, and masonry bonding layer. A multi-technique analytical framework (XRF, XRD, TG, and SEM) was employed to characterize chemical composition, mineral phases, thermal behavior, and microstructure. Results reveal a deliberate “functional adaptability” material design. The surface layer adopts a rigid protective formulation with high quartz (76.9%) and CaO (17.06%), forming a dense, low-porosity matrix resistant to abrasion and weathering. The wall core exhibits a flexible filling strategy with high porosity (35.44%), enabling moisture dissipation and deformation accommodation. The bonding layer, enriched in kaolinite (~29.8%) and reactive Al–Fe components, promotes pozzolanic reactions that generate hydraulic gels, ensuring durable interfacial adhesion under humid coastal conditions. These findings demonstrate that ancient builders engineered zone-specific material compositions to meet distinct structural and environmental demands, forming a functionally graded system analogous to modern material design concepts. This study provides a scientific basis for adopting partitioned, differentiated restoration strategies in coastal heritage conservation.