This work shows the structural symmetry differences affecting optical performance in cesium cadmium vanadate oxychlorides, indicating a new design approach for functional materials.
Cl act as the pivotal driver, triggering the remarkable differentiation in structural symmetry and thus the drastic divergence of their optical performances. This work enriches and expands the optical materials in the transition metal vanadate halides, shedding light on the structural design strategy via stoichiometric ratio regulation for functional NLO materials.
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Xu et al. (2026) studied this question.
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