Reveals how excess electrons inhibit methoxy photooxidation in TiO2 photocatalysis, indicating crucial roles in reaction dynamics.
photooxidation is inhibited by excess electrons significantly. Furthermore, excess electrons originating from both surface and near-surface (not only several atomic layers) play similar roles in the hole-mediated reactions by trapping photogenerated holes. The results not only deepen our understanding of the photocatalytic reactions but also provide valuable insights into how excess electrons regulate photocatalytic reactions.
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Liu et al. (2026) studied this question.
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