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Kinetic control enhances crystal growth of a new cobalt structure, implying advances in material science.
Kinetic control of crystal growth in the presence of a coordinating ligand is critical for the formation of a new structure of elemental cobalt (ε-cobalt, the unit cell with the two different types of cobalt atoms is shown), which was discovered upon analyzing the metallic powder produced by the thermal decomposition of [Co2(CO)8] in solution in the presence of trioctylphosphane oxide [TOPO, Eq. (1)].
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Dinega et al. (1999) studied this question.
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