Either a metal atom or the phthalocyanine ligand is the site of the first oxidation of the heteronuclear triple-decker complexes of type 1, depending on whether they contain an oxidizable CeIII ion or not. Now the first X-ray structure of such a heteronuclear triple-decker complex (1, M Ce, M′ Gd, p oep) has also been achieved.
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Chabach et al. (1996) studied this question.
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