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During the mercury photo-sensitized hydrogenation of ethylene, the activation energy for the reaction 2C2H5=C2H6+C2H4 is ≥ 1.2 kcal/mole, while above 200°C, ethane formation accelerates with an activation energy of ≥ 10.5 kcal/mole for the reaction C2H5+H2=C2H6+H. Novelty: ClaimNovelty.CONFIRMATORY. Consensus alignment: ConsensusAlignment.SUPPORTS_CONSENSUS.

November 1, 1947The Journal of Chemical Physics

The Mercury (3P1) Photo-Sensitized Hydrogenation of Ethylene

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DLD. J. LeRoyCommissariat à l'Énergie Atomique et aux Énergies Alternatives AKAllan KahnIllinois Institute of Technology

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LeRoy et al. (1947) studied this question.

synapsesocial.com/papers/6a088e81280cd4e998e8c9ff https://doi.org/10.1063/1.1746342

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The Mercury (3P1) Photo-Sensitized Hydrogenation of Ethylene

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The Mercury (3P1) Photo-Sensitized Hydrogenation of Ethylene

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