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N-(Trifluoromethylsulfonyl)arenesulfonimidoyl chlorides 3a-e and N,N′-bis(trifluoromethylsulfonyl)arenesulfonodiimidoyl chlorides 6a-e are obtained by N,N-dichlorotrifluoromethanesulfonamide oxidative imination of arene sulfonyl chlorides 1a-e and diaryl disulfides 4a-e, respectively. The electron nature of the new substituents possessing high electron-accepting ability is also determined.
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YAGUPOL'SKII et al. (1992) studied this question.
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