Analysis explores degeneracy effects and correlation energies in second-row isoelectronic atoms, suggesting important similarities with first-row counterparts.
The degeneracy effects in the isoelectronic series of the second-row atoms are analyzed. New values are estimated for the correlation energies. The correlation energy diagram exhibits a remarkable similarity with the corresponding one for first-row atoms and ions. We have added a new table of data which summarizes the results for the first- and second-row correlation energies. These data make use of previously unpublished computations on the relativistic effects.
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Veillard et al. (1968) studied this question.
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