A coordinated metal center aids water solubility of a supramolecular fullerene assembly. Two cyclodextrins rings are bridged back-to-back in one unit, and these units form an end-to-end intermolecular inclusion complex with fullerene to produce an intermolecular polyfullerene (see picture). Under the right conditions the assembly acts as an efficient photodriven DNA-cleavage reagent. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z52973_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Liu et al. (2004) studied this question.
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