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February 17, 1999Journal of the American Chemical Society

Evidence for Large Inner Reorganization Energies in the Reduction of Diaryl Disulfides:  Toward a Mechanistic Link between Concerted and Stepwise Dissociative Electron Transfers?

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Authors

KDKim DaasbjergNovo Nordisk (Denmark)HJHenrik JensenUniversity of CopenhagenRBRois BenassiUniversity of Modena and Reggio Emilia

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Daasbjerg et al. (1999) studied this question.

synapsesocial.com/papers/6a0c7c85c63d985fc0885a67https://doi.org/10.1021/ja983374p
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Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1On the Occurrence of Electron Transfer in Aliphatic Nucleophilic Substitution.1991 · 42 citations
  2. 2Evidence for the Transition between Concerted and Stepwise Heterogeneous Electron Transfer−Bond Fragmentation Mechanisms1997 · 90 citations
  3. 3First Determination of the Standard Potential for the Dissociative Reduction of the Antimalarial Agent Artemisinin1998 · 56 citations
  4. 4Passage from Concerted to Stepwise Dissociative Electron Transfer as a Function of the Molecular Structure and of the Energy of the Incoming Electron. Electrochemical Reduction of Aryldialkyl Sulfonium Cations1994 · 136 citations
  5. 5Reduction of Di-tert-Butyl Peroxide: Evidence for Nonadiabatic Dissociative Electron Transfer1995 · 89 citations