Rapid and Modular 1,2-Carboheterofunctionalization of Diverse Alkenes via Photoredox and RLT Catalysis

Seok Beom Lee; Hyungwoo Choi; Junhwa Hong; Jinwoo Lee; Joonseok Jang; Sangmyung Han; Suckchang Hong

doi:10.1039/d6qo00522e

January 1, 2026Organic Chemistry Frontiers

Rapid and Modular 1,2-Carboheterofunctionalization of Diverse Alkenes via Photoredox and RLT Catalysis

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Key Points

The aim is to develop a reaction system for the 1,2-carboheterofunctionalization of alkenes using photoredox and RLT catalysis.
Developed a mild photoredox reaction system
Implemented iron-mediated radical ligand transfer
Accommodated a broad substrate scope for diverse alkenes.
Successfully achieved carboheterofunctionalization with high efficiency
Demonstrated versatility across various alkene substrates
Enabled selective functionalization under mild conditions.

Implication

Demonstrates a novel photoredox and RLT approach for transforming alkenes, suggesting versatile applications in organic synthesis.

Abstract

We developed a mild photoredox- and iron-mediated radical ligand transfer (RLT) reaction system that enables the direct 1,2-carboheterofunctionalization of alkenes with a broad substrate scope. This transformation accommodates diverse radical...

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Cite This Study

Lee et al. (2026) studied this question.

synapsesocial.com/papers/6a0d4efcf03e14405aa9a3fd https://doi.org/10.1039/d6qo00522e

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Rapid and Modular 1,2-Carboheterofunctionalization of Diverse Alkenes via Photoredox and RLT Catalysis

Key Points

Implication

Abstract

Discussion

Cite This Study

Rapid and Modular 1,2-Carboheterofunctionalization of Diverse Alkenes via Photoredox and RLT Catalysis

Key Points

Implication

Abstract

Discussion

Cite This Study

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