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Hydrogen-atom transfer (HAT) counts amongst the most widely investigated routes to carbon-centered radicals. Intramolecular processes involving 1,5-HAT are widespread to promote regioselective radical "CH activation". The aim of this review is to draw up a comprehensive inventory of the less commonly encountered 1,n-radical translocations (n≠5) with the aim to update this topic with the most recent relevant data.
Nechab et al. (Fri,) studied this question.
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