Synthesis, structural and spectroscopic characterization of zinc(II) iodide complex with 2-[(4-iodophenyl)iminomethyl]pyridine in the solid state and solution †

Krzysztof Łyczko; Monika Łyczko; Elżbieta Bednarek; Mehdi Khalaj; Karolina Węgrzyńska; Anna Baraniak; Ingmar Persson

doi:10.1039/d6nj01605g

January 1, 2026New Journal of Chemistry

Synthesis, structural and spectroscopic characterization of zinc(II) iodide complex with 2-[(4-iodophenyl)iminomethyl]pyridine in the solid state and solution †

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Key Points

The research aims to synthesize and characterize a zinc(II) iodide complex involving a Schiff base ligand.
Synthesis of the zinc iodide complex using ZnI2 and 2-[(4-iodophenyl)iminomethyl]pyridine.
Characterization conducted through structural and spectroscopic techniques in solid state and solution.
Crystallization was confirmed to occur in the monoclinic space group P21/c.
Successful synthesis of [ZnI2(L4-I)], a novel zinc(II) iodide complex.
Complex crystallizes in the monoclinic space group P21/c, indicating a stable structure.
Characterization reveals insights into the structural parameters and binding interactions of the complex.

Implication

Synthesis reveals structural details of a zinc iodide complex, implying potential applications in coordination chemistry.

Abstract

The title compound [ZnI 2 (L 4-I )] has been prepared using the Schiff base 2-[(4-iodophenyl)iminomethyl]pyridine (L 4-I ) and ZnI 2 , and crystallizes in the monoclinic space group P2 1 /c (no. 14). Zinc binds two N...

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Łyczko et al. (2026) studied this question.

synapsesocial.com/papers/6a0ea17cbe05d6e3efb602a7 https://doi.org/10.1039/d6nj01605g

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Synthesis, structural and spectroscopic characterization of zinc(II) iodide complex with 2-[(4-iodophenyl)iminomethyl]pyridine in the solid state and solution †

Key Points

Implication

Abstract

Discussion

Cite This Study

Synthesis, structural and spectroscopic characterization of zinc(II) iodide complex with 2-[(4-iodophenyl)iminomethyl]pyridine in the solid state and solution †

Key Points

Implication

Abstract

Discussion

Cite This Study

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