Expanded benzo-fused dihydro-azulenoazulenes -Tuning electronic properties

Cecilie Rindom; Frédéric Lirette; J. Ouellette; Florim Seljmani; Viktor Bliksted Roug Pedersen; Jean-Francois Morin; Mogens Brøndsted Nielsen

doi:10.1039/d6cc02835g

January 1, 2026Chemical Communications

Expanded benzo-fused dihydro-azulenoazulenes -Tuning electronic properties

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Key Points

The aim is to explore how expanding benzo-fused dihydroazulenoazulenes alters their electronic properties.
Expanded benzo-fused 4,5-dihydroazulenoazulenes through longitudinal ring fusion and transverse dithiafulvene incorporation.
Characterized the resulting π-systems to assess changes in optical and electrochemical properties.
The modified compounds exhibited significantly altered optical and electrochemical properties.
Characterization revealed enhancements in electronic behavior compared to their non-modified counterparts.

Implication

This work demonstrates altered optical and electrochemical properties in new benzo-fused compounds, highlighting their potential applications.

Abstract

In this work, benzo-fused 4,5-dihydroazuleno[2,1,8ija]azulenes were expanded through longitudinal ring fusion and transverse incorporation of dithiafulvene donor units. The resulting non-benzenoid π-systems exhibit markedly altered optical and electrochemical properties, including...

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Cite This Study

Rindom et al. (2026) studied this question.

synapsesocial.com/papers/6a0ff3aed674f7c03778c7a9 https://doi.org/10.1039/d6cc02835g

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Expanded benzo-fused dihydro-azulenoazulenes -Tuning electronic properties

Key Points

Implication

Abstract

Discussion

Cite This Study

Expanded benzo-fused dihydro-azulenoazulenes -Tuning electronic properties

Key Points

Implication

Abstract

Discussion

Cite This Study

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