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May 22, 2026Open Access

Development of strongly photoreducing, high triplet energy iridium(III) NHC complexes for use in photocatalysis

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Authors

MGMaire Ailis Griffin

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Overview

Thesis explores novel iridium(III) photocatalysts for enhanced photocatalysis, indicating significant advancements in efficiency.

Key Points

  • The research aims to develop iridium(III) complexes with improved photophysical properties for effective photocatalysis.
  • Developed novel iridium(III) NHC complexes with enhanced triplet energy and photoreducing ability.
  • Conducted stability and performance comparisons against established photocatalysts like fac-Ir(ppy)₃.
  • Utilized DFT computational study for rationalizing the photophysical properties of new complexes.
  • The mer-Ir(pmp)₃ complex showed superior performance as a photocatalyst under blue-light excitation.
  • Ir(dFppy)₂(pmi) demonstrated enhanced efficacy in dual nickel/photoredox cross-coupling reactions.
  • Higher yields in C-H borylation under photochemical conditions were observed, confirmed by both experimental and computational analysis.

Cite This Study

Maire Ailis Griffin (2026) studied this question.

synapsesocial.com/papers/6a0ff3ecd674f7c03778ccfchttps://doi.org/10.17630/sta/1640
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