Silver benzenesulfonate is an example of a layered ‘inorgano–organic’ solid where the inorganic component is comprised of sulfonate-bridged silver(I) centers and the organic moiety is a phenyl group; the resulting network of silver ions forms a planar hexagonal array incorporating a previously unobserved six-fold metal-bridging mode for the sulfonate ion.
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Shimizu et al. (1999) studied this question.
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