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Using a flexible version of a rigid-molecule model of water we have analyzed the velocity autocorrelation functions to investigate the effect of the liquid milieu on the high-frequency internal modes of molecular motion. The calculations have been made at 1 g cm^-3 and at 250, 325, and 375 K. Good agreement with experimentally determined pair correlations has also been found.
Toukan et al. (1985) studied this question.