Amorphous silicon (a-Si:H) based solar cells are highly interesting in the context of hybrid (i.e. photovoltaic/thermal) solar energy conversion. First, their large area capability and the variety of possible substrate materials permit to apply a-Si:H PV modules directly on the surface of conventional heat collectors at low cost. Further, the low temperature coefficient of a-Si:H cells (0.1%/K) allows operation of a-Si:H solar modules at temperatures as high as 100/spl deg/C without substantial power loss. The authors focus on the thermal performance of such hybrid collectors based on a-Si:H cells, with emphasis on a ZnO coat on top of the solar cell. ZnO can be "tuned" to absorb the infrared part of sunlight and, at the same time, its emission coefficient for heat-radiation is nearly as low as that of the optimized selective surfaces used in thermal collectors. The authors propose a collector structure with a high potential for thermal conversion efficiency while maintaining high electrical conversion efficiency.
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Platz et al. (2002) studied this question.
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