Modulating Ligand-to-Metal Charge Transfer in Titanium-Oxo Clusters Enables Efficient H ₂ O ₂ Activation and Pollutant Degradation

Zihang Wang; Wenxin Peng; Jintao Geng; Hui Wang; Xiaodong Zhang; Yi Xie

doi:10.1039/d6qi00774k

January 1, 2026Inorganic Chemistry Frontiers

Modulating Ligand-to-Metal Charge Transfer in Titanium-Oxo Clusters Enables Efficient H ₂ O ₂ Activation and Pollutant Degradation

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Key Points

To investigate how modulating ligand-to-metal charge transfer in titanium-oxo clusters influences their efficiency in catalyzing hydrogen peroxide activation and pollutant degradation.
Utilized a series of titanium-oxo clusters with varying ligand compositions and structural modifications.
Conducted analyses to evaluate their catalytic performance in hydrogen peroxide activation and pollutant degradation.
Established structure-activity relationships to correlate modifications with performance outcomes.
Modified titanium-oxo clusters increased hydrogen peroxide activation rates compared to unmodified clusters (specific rates not provided).
Enhanced pollutant degradation efficiency observed with optimized ligand configurations.
Positive correlation identified between ligand modification and catalytic efficiency, supporting proposed theory.

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Implication

Demonstrates efficient pollutant degradation using modified titanium-oxo clusters, suggesting improved catalytic performance.

Abstract

Titanium-oxo clusters (TOCs), featuring atomically precise structures and tunable electronic properties, provide an ideal model for elucidating structure-activity relationships in heterogeneous Fenton-like catalysis. In this work, a series of titanium‑oxo...

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Wang et al. (2026) studied this question.

synapsesocial.com/papers/6a1a81e00307b78509433aef https://doi.org/10.1039/d6qi00774k

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Modulating Ligand-to-Metal Charge Transfer in Titanium-Oxo Clusters Enables Efficient H ₂ O ₂ Activation and Pollutant Degradation

Key Points

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Implication

Abstract

Discussion

Cite This Study

Modulating Ligand-to-Metal Charge Transfer in Titanium-Oxo Clusters Enables Efficient H ₂ O ₂ Activation and Pollutant Degradation

Key Points

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Implication

Abstract

Discussion

Cite This Study

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