Organic Ammonium Flexibility Modulated Phase-Transition Behaviour in 3D Perovskite-like Mixed-valence Iron Complexes

Chang-Lei Ma; Chang Li; Jiayue Sun; Rui‐Rui Han; 刘福臣; Jiong-Peng Zhao; Zhao Quan Yao

doi:10.1039/d6cc02195f

January 1, 2026Chemical Communications

Organic Ammonium Flexibility Modulated Phase-Transition Behaviour in 3D Perovskite-like Mixed-valence Iron Complexes

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Key Points

This research aims to understand how organic ammonium modifies phase-transition behavior in mixed-valence iron complexes.
Synthesized novel perovskite-like antiferromagnets with different organic ammonium
Modified connectivity of formate perovskites using oxalate
Identified significant changes in the phase-transition behavior due to organic ammonium modifications
New material types show varied electrical properties linked to π-conjugated systems

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Implication

Demonstrates phase-transition changes in 3D iron complexes, indicating the impact of organic ammonium modifications.

Abstract

By employing oxalate to modify the connectivity of formate perovskites, novel perovskite-like cai topological 3D antiferromagnets [A]2[FeIIIFeII2(HCOO)7(C2O4)] with different organic ammonium were synthesized. The reduction of π-conjugated systems in organic...

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Ma et al. (2026) studied this question.

synapsesocial.com/papers/6a1a820e0307b78509433d15 https://doi.org/10.1039/d6cc02195f

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Organic Ammonium Flexibility Modulated Phase-Transition Behaviour in 3D Perovskite-like Mixed-valence Iron Complexes

Key Points

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Implication

Abstract

Discussion

Cite This Study

Organic Ammonium Flexibility Modulated Phase-Transition Behaviour in 3D Perovskite-like Mixed-valence Iron Complexes

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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