An Ambipolar Conducting Covalent Organic Framework with Self‐Sorted and Periodic Electron Donor‐Acceptor Ordering

A donor-acceptor built-in covalent organic framework with segregated, periodic, and bicontinuous electron donor-acceptor ordering is reported. The framework consists of pre-organized periodic independent pathways for ambipolar electron and hole conduction and constitutes vertically ordered p-n heterojunctions with a broad D-A interface for enhanced photoconductivity. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.