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Supported Rh10Se catalyst on TiO2 converted carbon dioxide into ethanol faster (60 × 10–3 mol h–1 g cat–1) and more selectively (≈83%) than other supported Rh clusters or Rh10Se on other inorganic oxides, presumably due to the effects of interstitial Se and the interface of the Rh10Se cluster and TiO2.
Kurakata et al. (Mon,) studied this question.