Assessment of the water quality in the coastal Yaqui valley (Mexico): Implications for human health and ecological risks

This study examines the water quality in the Yaqui Valley in Mexico, a semi-arid region impacted by mining, agriculture, and aquaculture. Contamination sources, health risks and ecological impacts are investigated. Freshwater was found to be contaminated by dissolved As, presumed to result from mining activities in the mountains. Drainage water revealed an overall contamination by dissolved As and by suspended particles enriched with Al, Fe and Mn, associated with runoff processes. Intermittent contamination of drainage water by Cu, K + , NO 3 − and PO 4 3− is attributed to the use of fertilizers or pesticides. In the coastal area, drainage water contains high concentrations of Na, Ca, SO 4 2− and Cl, related to salinization processes, as well as higher concentrations of dissolved As, related to solid/liquid interactions that are enhanced by salinization. This drainage water discharges into the bay, degrading the seawater quality and increasing ecological risks. Outputs of this study can serve as a reference for the protection of this economically important coastal ecosystem. Concerning health risks, this study demonstrates that groundwater is also contaminated by dissolved As, believed to be associated with transfers from the geological basement to the dissolved phase of water, and other major chemicals related to salinization processes. The findings indicate that ingesting the groundwater poses a significant risk to human health with a primary exposure risk associated with dissolved As, particularly among children. This study presents crucial data for the Yaqui population, water managers and researchers, and provides novel insights into the management and mitigation of the identified risks. • Mining, agriculture and salinization are damaging the water quality. • Ingesting water enriched with dissolved As is the main health risk. • Suspended particles enriched with Al and Fe threatens surface water quality. • Salinization promotes the transfer of As from solid to dissolved species. • Ecological risks due to significant chemical fluxes from drainage waters.