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Back to basics: The principle of microscopic reversibility is the basis of a new screening method for chiral catalysts. Monitoring the back reaction of quasienantiomeric allylation products by ESI-MS reveals the intrinsic enantioselectivity of palladium catalysts in allylic substitution reactions (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z705081_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Müller et al. (2008) studied this question.
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