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Abstract The development of conversion‐typed anodes with ultrafast charging and large energy storage is quite challenging due to the sluggish ions/electrons transfer kinetics in bulk materials and fracture of the active materials. Herein, the design of porous carbon nanofibers/SnS 2 composite (SnS 2 @N‐HPCNFs) for high‐rate energy storage, where the ultrathin SnS 2 nanosheets are nanoconfined in N‐doped carbon nanofibers with tunable void spaces, is reported. The highly interconnected carbon nanofibers in three‐dimensional (3D) architecture provide a fast electron transfer pathway and alleviate the volume expansion of SnS 2 , while their hierarchical porous structure facilitates rapid ion diffusion. Specifically, the anode delivers a remarkable specific capacity of 1935.50 mAh g −1 at 0.1 C and excellent rate capability up to 30 C with a specific capacity of 289.60 mAh g −1 . Meanwhile, at a high rate of 20 C, the electrode displays a high capacity retention of 84% after 3000 cycles and a long cycle life of 10 000 cycles. This work provides a deep insight into the construction of electrodes with high ionic/electronic conductivity for fast‐charging energy storage devices.
Liang et al. (Sat,) studied this question.