Reports crystallographic phase transformation in MgAl2O4, suggesting its importance in material science.
A new crystallographic phase transformation in MgAl2O4 is reported in which the low-temperature low-symmetry space group of MgAl2O4 transforms to the 'spinel' space group Fd3m at ~ 450 °C. The in situ electron diffraction experiments suggest that this is a second-order phase transformation.
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Mishra et al. (1977) studied this question.
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