Synapse
⌘+K
Synapse
PulseExploreClubsResearchersJournals
Instagram
HomeClubsExplore
May 1, 1997Journal of the American Chemical Society

Catalysis by Organic Solids. Stereoselective Diels−Alder Reactions Promoted by Microporous Molecular Crystals Having an Extensive Hydrogen-Bonded Network

View Full Paper
Ask AI
Bookmark
Share

Authors

KEKen EndoSony Computer Science LaboratoriesTKTakashi KoikeShimane UniversityTSTomoya SawakiKyoto University

Discussion

Loading...

Member takes

Implication

Randomized trial demonstrates stereoselective catalytic reactions in organic solids, suggesting novel material benefits.

Key Points

  • This research explores a new organic network material that catalyzes Diels−Alder reactions in the solid state.
  • Utilized anthracenebisresorcinol derivative 1 as a catalyst for Diels−Alder reactions.
  • Investigated the mechanism involving sorption, intracavity reaction, and product desorption.
  • Analyzed the kinetic properties and effects of pulverization through X-ray crystallography.
  • Catalyst 1 effectively promoted Diels−Alder reactions, demonstrating notable stereoselectivity.
  • Mechanism involved prearrangement of reactants within the microporous structure, enhancing reaction kinetics.
  • Stereoselective reactions were supported for alkyl acrylates, although not catalytic in that case.

Cite This Study

Endo et al. (1997) studied this question.

synapsesocial.com/papers/6a202291c705fa157d0db76dhttps://doi.org/10.1021/ja964198s
View Full Paper
Ask AI
Bookmark
Share

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Photochemical reactions of organic crystals1987 · 948 citations
  2. 2Acceleration and selectivity enhancement of Diels-Alder reactions by special and catalytic methods1993 · 408 citations
  3. 3Crystal lattice control of unimolecular photorearrangements1980 · 52 citations
  4. 4Catalytic asymmetric Diels Alder reactions1992 · 836 citations
  5. 5Photodimerization in the solid state1971 · 2,104 citations