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The current distribution and overall polarization behavior of electrodeposition at a flow-through (packed bed or fluidized bed) electrode are modeled by means of a one-dimensional model involving a primary reacting species and a simultaneous side reaction. The model equations are solved by orthogonal collocation; the time and storage requirements compare favorably to those of finite-difference methods. Experimental data obtained using a packed-bed electrode are compared with the model predictions and various methods of fitting the data are compared. KEYWORDS: Packed-bed electrodesPolarizationOrthogonal collocation Additional informationNotes on contributorsJ. ROBERT SELMAN To whom correspondence should be addressd
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Yuh et al. (1985) studied this question.
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