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A new type of potential function is derived from the atomic Hartree-Fock self- consistent potential which has almost identical occupied orbitals, but an adjustable set of unoccupied bound orbitals. Comparisons are made between the properties of this potential and the Hartree-Fock potential for trivalent praesodymium. It is shown that the use of the new potential introduces considerable simplifications into atomic configuration interaction calculations.
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Newman et al. (1972) studied this question.
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