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The advancement of intelligent ecosystems depends upon not only technological innovation but also a multidimensional understanding of material-world interactions. This theoretical transformation prompts increasing demands for multifunctional materials exhibiting hierarchical organization across multiple length scales. Inorganic nanofibers demonstrate potential in bridging the gap between microscale and macroscale through their three-dimensional architectures. However, their inherent brittleness, primarily resulting from inferior structural integrity poses, significantly limits their current applications. This critical limitation highlights the urgent necessity for developing fabrication strategies that simultaneously enhance the mechanical flexibility and robustness, ensuring reliable performance under extreme operational conditions. This comprehensive review systematically examines brittle mechanism fracture through multiscale analysis including molecular, nanoscale, and microscale dimensions. It presents innovative methodologies integrating simulation-guided structural design with advanced in situ characterization techniques capable of real-time monitoring under a practical stress-strain process. Furthermore, the discussion progresses to address contemporary challenges and emergent solutions in oxide nanofiber engineering, providing strategic insights for developing mechanically robust flexible systems with stable functional properties. Ultimately, this review examines the potential of inorganic nanofibers to overcome the limitations of nano powder materials and achieve their promising real-world applications.
Li et al. (Mon,) studied this question.