The isotropic hfs constants of F‐centers in alkaline‐earth fluorides and the g ‐shift in CaF 2 are calculated using various published wave functions. The computed results of these calculations are then compared with experiment in order to assess the validity of the wave functions. The wave functions studied give the correct order of magnitude for the isotropic hfs constants of the first shell of F − ‐ions surrounding the vacancy. For the second shell of F − ‐ions a few wave functions give values in agreement with experiment.
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Hartog et al. (1967) studied this question.
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