Spectroscopic study reveals that interactions dominate properties in aqueous dimethyl sulphoxide solutions.
This spectroscopic and thermodynamic study of aqueous dimethyl sulphoxide (DMSO) suggests that the properties of the system are dominated by direct component interaction. Maximum inter-action occurs in the region of 0.35 mole fraction (DMSO) and “enhancement of water structure” by added solute is absent, except perhaps at very low concentration, < 0.01 mole fraction. The excess enthalpy HE, is compared with literature values.
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Fox et al. (1975) studied this question.
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