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Single‐crystal X‐ray crystallography is employed to characterize the reaction species of a full catalytic carbonylation cycle within a Mn II ‐based metal–organic framework (MOF) material. The structural insights explain why the Rh metalated MOF is catalytically competent toward the carbonylation of MeBr but only affords stoichiometric turn‐over in the case of MeI. This work highlights the capability of MOFs to act as platform materials for studying single‐site catalysis in heterogeneous systems.
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Burgun et al. (2017) studied this question.
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