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Demonstrates atom-exchange reactions in aryliodonium salts, indicating potential for bioactive molecules.
With tosyloxy (-OTs) substituted monocyclic aryliodonium salts, we explored the atom-exchange reactions between sulfur/selenium/tellurium and iodine atoms for constructing benzo[b]-fused heterocycles such as benzo[b]thiophenes, benzo[b]selenophenes, and benzo[b]tellurophenes. The modifiable -OTs group of these benzo[b]-fused heterocycles enables straightforward diversification, providing a versatile platform for accessing bioactive molecules with potential application as antibacterial agents.
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Liu et al. (2026) studied this question.
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