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CO2 is included: The one-dimensional coordination polymer host Rh2(O2CPh)4(pyz)n (pyz=pyrazine; see picture, left) undergoes a reversible phase transition under cooling that is induced by CO2 adsorption to give an inclusion complex, in which up to three CO2 molecules per polymer unit reside within channels (right).
Takamizawa et al. (Wed,) studied this question.
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