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November 20, 2012Inorganic Chemistry250 citations

Biomimetic Catalysis of a Porous Iron-Based Metal–Metalloporphyrin Framework

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YCYao ChenTHTran HoangSMShengqian Ma

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Abstract

A porous metal-metalloporphyrin framework, MMPF-6, based upon an iron(III)-metalated porphyrin ligand and a secondary binding unit of a zirconium oxide cluster was constructed; MMPF-6 demonstrated interesting peroxidase activity comparable to that of the heme protein myoglobin as well as exhibited solvent adaptability of retaining the peroxidase activity in an organic solvent.

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Chen et al. (2012) studied this question.

synapsesocial.com/papers/6a21623757668066d6c3f504https://doi.org/10.1021/ic301923x
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