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Similar wormlike palladium nanocrystals are produced by various synthetic methods such as reverse micelles and phase-transfer reactions. Palladium nanocrystals, stabilized by dodecylamine as a coating agent, are produced by chemical reduction of PdCl2 by sodium borohydride, NaBH4. A soft digestive ripening process, without any reflux, in which wormlike palladium particles go to sphere is observed in the presence of a rather large amount of dodecanethiol. The wormlike particle diameter is similar to that of the spheres produced.
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Naoe et al. (2007) studied this question.
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