Randomized trial reveals distinct helical conformational polymorphs in coordination polymers, suggesting novel structural applications.
In the pair of helical conformational polymorphs of the coordination polymer {[AgL](CF3SO3)}infinity(L=2-pyridinyl-3-pyridinylmethanone), the 2(1) helices of opposite chirality in one supramolecular isomer are stacked alternately to form a racemate, while the 4(1) helices in the other are assembled homochirally by inter-chain argentophilic interaction to generate a conglomerate.
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Chen et al. (2005) studied this question.
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