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Abstract It is challenging to obtain a material that can detect photons ranging from X‐rays to infrared light. Such materials have promising use to develop advanced applications like in information storage, anticounterfeiting, or X‐ray imaging. This article reports on such a material; LiTaO 3 : x Bi 3+ , y Dy 3+ perovskite phosphor. Experimental spectroscopy, thermoluminescence, and vacuum referred binding energy diagram (VRBE) construction are combined to study the trapping processes of charge carriers. The VRBEs in the ground or excited states of Bi 3+ and Bi 2+ are discussed. Bi 3+ emerges to act as a ≈1.3 eV deep hole capturing center and it may possibly also act as a 0.80 ± 0.5 eV deep electron trapping center. A linear relation between the amount of stored charge carriers and a photochromic phenomenon both induced by X‐rays or 254 nm UV‐light charging appears. The stored charge carriers in LiTaO 3 : x Bi 3+ , y Dy 3+ are removed by heating or with an optically stimulated process with 365 nm UV light to 850 nm infrared laser. More than 3 or 40 h of Bi 3+ and Dy 3+ based white afterglow is measurable in LiTaO 3 :0.005Bi 3+ ,0.004Dy 3+ after exposure to X‐rays or 254 nm UV light. Proof‐of‐concept light detection applications like 2D information storage and anticounterfeiting or X‐ray imaging are demonstrated by using the phtotochromic and white afterglow LiTaO 3 : x Bi 3+ , y Dy 3+ phosphors.
Lyu et al. (Tue,) studied this question.