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October 1, 1976Journal of the American Chemical Society208 citations

Kinetic applications of electron paramagnetic resonance spectroscopy. 27. Isomerization of cyclopropylcarbinyl to allylcarbinyl

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BMB. MaillardDFD. ForrestKIK. U. Ingold

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Abstract

The rate constant for isomerization of cyclopropylcarbinyl to allylcarbinyl has been measured by EPR spectroscopy. It can be represented by: log(ki/s-1) = (12.48 ± 0.85) - (5.94 ± 0.57)/θ, where θ = 2.3RT kcal/mol. This reaction is compared with other primary alkyl radical isomerizations.

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Cite This Study

Maillard et al. (1976) studied this question.

synapsesocial.com/papers/6a21f7711451ae9ed3e21ff1https://doi.org/10.1021/ja00438a047
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