Three-Dimensional Hierarchical Flowerlike α-Fe₂O₃ Nanostructures: Synthesis and Ethanol-Sensing Properties

The α-Fe(2)O(3) hierarchical nanostructures have been successfully synthesized via a simple solvothermal method. The as-prepared samples are loose and porous with flowerlike structure, and the subunits are irregularly shaped nanosheets. The morphology of the α-Fe(2)O(3) structures was observed to be tunable as a function of reaction time. To demonstrate the potential applications, we have fabricated a gas sensor from the as-synthesized hierarchical α-Fe(2)O(3) and investigated it for ethanol detection. Results show that the hierarchical α-Fe(2)O(3) sensor exhibits significantly improved sensor performances in comparison with the compact α-Fe(2)O(3) structures. The enhancement of sensing properties is attributed to the unique porous and well-aligned nanostructure.