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June 5, 2026Food Additives & Contaminants Part A0 citationsOpen Access

A sensitive method for the determination of novel derivatised thyrostat residues in urine by using UHPLC-MS/MS

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PMPhilip MullenAgri Food and Biosciences InstituteMWM. WalkerAgri Food and Biosciences InstituteAGAnna GadajAgri Food and Biosciences Institute

Key Points

  • This study aims to develop a sensitive method for detecting novel derivatised thyrostat residues in urine samples.
  • Utilized ultra-high-performance liquid chromatography coupled with tandem mass spectrometry (UHPLC-MS/MS) for analysis.
  • Focused on novel derivatised compounds including 2-thiouracil and 4-thiouracil.
  • Explored method performance against minimum method performance requirements (MMPR) of 10 µg L.
  • Developed method shows improved sensitivity for detecting trace thyrostat residues in urine.
  • Detection of novel derivatised residues provides significant advantages over traditional approaches.
  • Achieved limits of detection that meet or exceed regulatory standards, enhancing food safety measures.

Abstract

Thyrostats increase water retention and absorption in animals; this property is abused in the rearing of meat producing animals to inflate carcase weight in a bid to increase the profits of producers. As such meat is of poor quality, and due to the potential carcinogenic and teratogenic properties of thyrostats, their use has been banned in the EU since 1981. The difficulties encountered in the analysis of these compounds, due to their small size, high polarity, and the endogenous nature of some analytes (2-thiouracil, 4-thiouracil, 5-methylthiouracil), has limited the sensitivity of methods in difficult matrices such as urine, with minimum method performance requirements (MMPR) of 10 µg L

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Cite This Study

Mullen et al. (2026) studied this question.

synapsesocial.com/papers/6a22672f763171746d545e67https://doi.org/10.1080/19440049.2026.2665681
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