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Demonstrates high-yield synthesis of tetrasubstituted epoxides, indicating broad application potential.
-catalyzed [2 + 1] annulation of alkynyl acylsilanes with aryl diazoacetates has been developed, affording a wide range of functionalized tetrasubstituted epoxides in high yields. This method features broad substrate scope, excellent functional group compatibility, and gram-scale scalability. The synthetic utility of the resulting epoxides is also demonstrated by diverse chemical transformations.
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Li et al. (2026) studied this question.
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