Spin-lattice relaxation of copper and vanadyl porphyrins in extended molecular framework materials

Yukina Suzuki; Kazunobu Sato; Masanori Wakizaka; Ryota Sakamoto; Masahiro Yamashita

doi:10.1039/d6dt00996d

January 1, 2026Dalton Transactions

Spin-lattice relaxation of copper and vanadyl porphyrins in extended molecular framework materials

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Key Points

This research aims to analyze the spin-lattice relaxation times of copper and vanadyl porphyrins within various extended framework materials.
Investigation of T₁ times of Cu(II) and VO(IV) porphyrins in different types of frameworks
Analysis of covalent, hydrogen-bonded, and metal-organic frameworks as molecular spin qubits
Characterization of distinct spin-lattice relaxation behaviors across various materials
Identification of framework influences on relaxation times

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Implication

Investigates spin-lattice relaxation in copper and vanadyl porphyrins, indicating potential for molecular spin qubits.

Abstract

Spin-lattice relaxation times (T₁) of Cu(II) and VO(IV) porphyrins in extended framework materials (covalent, hydrogen-bonded, and metal–organic frameworks) are investigated as prototypical molecular spin qubits. All framework materials studied here...

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Suzuki et al. (2026) studied this question.

synapsesocial.com/papers/6a2268a7763171746d5474f3 https://doi.org/10.1039/d6dt00996d

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Spin-lattice relaxation of copper and vanadyl porphyrins in extended molecular framework materials

Key Points

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Implication

Abstract

Discussion

Cite This Study

Spin-lattice relaxation of copper and vanadyl porphyrins in extended molecular framework materials

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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