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Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation | Synapse

June 4, 2009Journal of the American Chemical Society590 citations

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Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

JHJonathan F. HullConcept Life Sciences (United Kingdom)DBDavid BalcellsUniversity of Bern JBJames D. BlakemoreArgonne National Laboratory

Key Points

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Abstract

A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

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Cite This Study

Hull et al. (Thu,) studied this question.

synapsesocial.com/papers/6a22b4d329c8bdba62cd5f8d https://doi.org/https://doi.org/10.1021/ja901270f

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