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The global commitment to ending hunger by 2030 has driven Colombia to align its Sustainable Development Goals (SDGs) toward reducing food waste and ensuring access to safe, nutritious food. A critical need is monitoring cumulative temperatures across food supply networks, prioritizing products over transport or storage infrastructure. This study introduces a Functional Time-Temperature Indicator (TTI) using nanodispersions of silver (Ag) and gold (Au) nanoparticles housed in 3D-printed plant-based resin containers. Nanoparticles were synthesized via three methods: in situ reduction (AgNPs), seed-based thermal synthesis (AgTNPs), and pulsed laser ablation in liquid (AuNPs). The TTIs operate through three colorimetric mechanisms: NP concentration, geometry changes, and agglomeration. At 4 °C, AgNPs and AgTNPs maintained stable color, while at 22 °C, they exhibited significant changes, with AgNPs reaching 252% variation within 5 h. AuNPs responded at lower temperatures, showing up to 27% variation. Containers enabled effective nanodispersion incorporation due to their thermal and optical properties. AgTNP-based TTIs demonstrated the most noticeable changes at 22 °C, with a total color difference (ΔE) of 39.9, easily detectable by observers. These TTIs provide robust solutions for continuous cold chain monitoring, enhancing food safety and preserving quality throughout the supply chain.
Lanza et al. (Sat,) studied this question.